Chlorotitanium Triisopropoxide 三异丙氧化氯钛
CAS 20717-86-6 MFCD00009861
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分类
- Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Titanium
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Solution Deposition Precursors, Titanium, 材料科学
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Titanium
相关文献及参考
- RegBook 1 (2), 3057:J / Structure Index 1 , 484:B:8
- Reacts with the Li enolates of ketones to give Ti(IV) enolates which undergo the aldol condensation with pronounced erythro-selectivity: Tetrahedron Lett., 22, 4691 (1981). This selectivity can be extended to aldehydes by using the Li derivatives of their N,N-dimethylhydrazones: Angew. Chem. Int. Ed., 21, 864 (1982).
- Merck 14 ,10481
- Fieser 14 ,87
- In combination with cyclopentylmagnesium bromide, forms a Ti(II) species which mediates the reaction of vinyltributyltin with esters or amides to give trisubstituted cyclopropylstannanes with high diastereoselectivity: J. Org. Chem., 63, 9135 (1998).
安全信息
GHS Symbol
- H228 Flammable solid 易燃固体
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
- R10 Flammable 易燃
- R48/20
- R34 Causes burns 会导致灼伤
- R62 Possible risk of impaired fertility 有削弱生殖能力的危险
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R51/53
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
- R11 Highly flammable 非常易燃
其他信息
- Alfa Aesar:三异丙氧化氯钛,95% Chlorotitanium triisopropoxide, 95%(20717-86-6)
- 三异丙氧基氯化钛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 224768000 三异丙氧基氯化钛 Chlorotitanium triisopropoxide , 1M solution in dichloromethane, AcroSeal® 800 ML 4093元 2010/06/21 224592500 三异丙氧基氯化钛 Chlorotitanium triisopropoxide 98% 250 GR 2451元 2010/06/21 224590010 三异丙氧基氯化钛 Chlorotitanium triisopropoxide 98% 1 KG 6929元
- TSCA:No
- Sigma Aldrich:20717-86-6(sigmaaldrich)
- Acros Organics:三异丙氧基氯化钛 Chlorotitanium triisopropoxide, 98%(20717-86-6)
- MOL 文件:20717-86-6.mol
- F:3-10-21
- 敏感性:Moisture Sensitive