Diethoxymethylsilane 甲基二乙氧基硅烷

CAS 2031-62-1 MFCD00026749

化学结构图

2031-62-1
SMILES: CCO[SiH](C)OCC

化学属性

Mol. FormulaC5H14O2Si
Mol. Weight134.25 g/mol
Density0.838
Refractive index1.3730 to 1.3770
Flash Point10°C(lit.)
TSCAYes
Boiling Point97°C(lit.)

别名和识别编码

Chemical NameDiethoxymethylsilane
Synonym DIETHOXYMETHYLSILANE Diethoxymethylsilane [Hydrosilylating Reagent] {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00026749
CAS Number2031-62-1
EC Number217-982-3
Beilstein Registry Number1733975
PubChem Substance ID6327387
Reaxys-RN1733975
Chemical Name Translation甲基二乙氧基硅烷
LabNetwork Molecule IDLN01741811
InChIKeySOGIFFQYRAXTDR-UHFFFAOYSA-N
InChIInChI=1S/C5H13O2Si/c1-4-6-8(3)7-5-2/h4-5H2,1-3H3
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分类

  • {SNA} Chemical Synthesis, Di-Alkoxy Silanes, Micro/NanoElectronics, Organometallic Reagents, Organosilicon, Others, Self Assembly & Contact Printing, Silane Coupling Agents/Adhesion Promoters, 材料科学
  • {SNA} Chemical Synthesis, Di-Alkoxy Silanes, Materials Science, Micro/NanoElectronics, Organometallic Reagents, Organosilicon, Others, Self Assembly & Contact Printing, Silane Coupling Agents/Adhesion Promoters
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chemical Synthesis, Di-Alkoxy Silanes, Micro/NanoElectronics, Organometallic Reagents, Organosilicon, Other Organosilicon,

相关文献及参考

  • Hydosilylation of olefinic compounds can be effected, e.g. in the presence
  • Short: III/38A
  • Silane reducing agent; see Appendix 4. In the presence of KF or CsF, reduces aldehydes and ketones to alcohols (via the silyl ether): Tetrahedron, 37, 2165 (1981). With CsF, the reaction can be extended to esters: Synthesis, 558 (1981). Both reactions are improved in DMSO or DMF as solvent: Synthesis, 981 (1982).
  • Short: EINECS
  • Short: IV/20B
  • Hydosilylation of olefinic compounds can be effected, e.g. in the presence of PtO2: Org. Lett., 4, 2117 (2002).

安全信息

Packing GroupII
UN Number UN 1993 3/PG 2 1993
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R11 Highly flammable 非常易燃
Safety Statements
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Storage condition Moisture Sensitive Flammables area
Hazard Codes F;Xi
GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard Class3

其他信息

  • 图谱信息:甲基二乙氧基硅烷(2031-62-1)核磁图( 13 CNMR) 甲基二乙氧基硅烷(2031-62-1)质谱(MS) 甲基二乙氧基硅烷(2031-62-1)核磁图( 1 HNMR) 甲基二乙氧基硅烷(2031-62-1)红外图谱(IR1)
  • 用途一:用于合成有机硅中间体及高分子化合物
  • Sigma Aldrich:2031-62-1(sigmaaldrich)
  • Acros Organics:甲基二乙氧基硅烷 Methyldiethoxysilane,97%(2031-62-1)
  • MOL 文件:2031-62-1.mol
  • Alfa Aesar:二乙氧基甲基硅烷,97% Diethoxymethylsilane, 97%(2031-62-1)
  • 甲基二乙氧基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2403 甲基二乙氧基硅烷[氢化硅化试剂] Diethoxymethylsilane [Hydrosilylating Reagent] 25ML 989元 2010/06/21 392260250 甲基二乙氧基硅烷 Methyldiethoxysilane 97% 25 GR 2504元 2010/06/21 392260050 甲基二乙氧基硅烷 Methyldiethoxysilane 97% 5 GR 725元
  • TCI Shanghai:甲基二乙氧基硅烷[氢化硅化试剂] Diethoxymethylsilane [Hydrosilylating Reagent],>;95.0%(GC)(2031-62-1)
  • MSDS 信息:Diethoxymethylsilane(2031-62-1).msds
  • 甲基二乙氧基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D2403 甲基二乙氧基硅烷[氢化硅化试剂] Diethoxymethylsilane [Hydrosilylating Reagent] 25ML 1120元 2010/06/21 392260250 甲基二乙氧基硅烷 Methyldiethoxysilane 97% 25 GR 2504元 2010/06/21 392260050 甲基二乙氧基硅烷 Methyldiethoxysilane 97% 5 GR 725元
  • 敏感性:Moisture Sensitive
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物