4-Nitrophenylboronic Acid 4-硝基苯基硼酸

CAS 24067-17-2 MFCD00161360

化学结构图

24067-17-2
SMILES: [O-][N+](=O)C1C=CC(=CC=1)B(O)O

化学属性

Mol. Formula(O2N)C6H4(B(OH)2)
Mol. Weight167
Melting Point285-290
TSCANo
Density1.422

别名和识别编码

Chemical Name4-Nitrophenylboronic Acid
CAS Number24067-17-2
Alfabeta NameNITROPHENYLBORONICACID 4-
MDL NumberMFCD00161360
Synonym p-Nitrophenylboronic acid 4-硝基苯硼酸 p-nitro-benzeneboronic acid 4-硝基苯基硼酸 4-Nitrophenylboronic acid 4-Nitrobenzeneboronic acid p-Nitrophenylboronic acid p-nitro-benzeneboronic acid 4-Nitrobenzeneboronic acid
PubChem Substance ID87559783
Reaxys-RN3530497
Beilstein Registry Number16(4)1670
EC Number250-023-7
Chemical Name Translation4-硝基苯基硼酸
LabNetwork Molecule IDLN00009603
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分类

  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. Tang, J-S.; et al. , Efficient palladium-catalyzed Suzuki-Miyaura cross-coupling of iodoethynes with arylboronic acids under aerobic conditions Synthesis 17 , 2789-2795, (2011)
  • 2. Dastbaravardeh, N.; Schnuerch, M.; Mihovilovic, M. D. , Ruthenium(0)-Catalyzed sp3 C-H Bond Arylation of Benzylic Amines Using Arylboronates Org. Lett. 7th ed., 14 , 1930-1933, (2012) 摘要
  • 3. Reus, C.; et al. , Synthesis of Bromo-, Boryl-, and Stannyl-Functionalized 1,2-Bis(trimethylsilyl)benzenes via Diels-Alder or C-H Activation Reactions J. Org. Chem. 7th ed., 77 , 3518-3523, (2012) 摘要
  • 4. Dieudonne-Vatran, A.; Azoulay, M.; Florent, J-C. , A new access to 3-substituted-1(2H)-isoquinolone by tandem palladium-catalyzed intramolecular aminocarbonylation annulation Org. Biomolecular Chem. 13th ed., 10 , 2683-2691, (2012)
  • 5. Gavade, S.; et al. , Cu(acac)2-catalyzed N-arylations of phenylurea with arylboronic acid Synth. Commun. 11th ed., 42 , 1704-1714, (2012)
  • 6. Wang, L.; et al. , An efficient copper-catalyzed one-pot synthesis of diaryl thioethers by coupling of arylboronic acids with potassium ethyl xanthogenate under mild conditions Synlett 20 , 3041-3045, (2011)
  • 7. Kim, J.; et al. , Copper-Mediated Sequential Cyanation of Aryl C-B and Arene C-H Bonds Using Ammonium Iodide and DMF J. Am. Chem. Soc. 5th ed., 134 , 2528-2531, (2012) 摘要
  • 8. Zhang, J.; et al. , Copper-catalyzed arylation of indolin-2,3-ones with arylboronic acids Tetrahedron 48th ed., 67 , 9347-9351, (2011)
  • 9. Nishino, T.; et al. , Regioselective glycosylation of unprotected methyl hexopyranoside by transient masking with arylboronic acid Heterocycles 2nd ed., 84 , 1123-1140, (2012)
  • 10. Marhadour, S.; et al. , An efficient access to 2,3-diarylimidazo[1,2-a]pyridines via imid

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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