CAS 1314-13-2 MFCD00011300-Zinc Oxide 氧化锌 TAO{mole}

Zinc Oxide 氧化锌

CAS 1314-13-2 MFCD00011300

化学结构图

SMILES: O=[Zn]

化学属性

TSCA	No
Melting Point	1975 °C
Density	5.61
Solubility	Insoluble in water. Soluble in dilute acetic acid, dilute mineral acids, ammonia, ammonium carbonate
Boiling Point	1949.9 °C at 760 mmHg
Refractive index	2.008
Stability	易吸潮.
Mol. Formula	OZn
Appearance	white pwdr.
Mol. Weight	81.38

别名和识别编码

Chemical Name	Zinc Oxide
EC Number	215-222-5
Synonym	Zinc oxide, 98% {LY} Zinc oxide, 98% {} {LY} Zinc oxide, 98% {} {} {LY} Zinc oxide, 98% {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	24855477
Merck Number	14,10147
Chemical Name Translation	氧化锌
InChIKey	XLOMVQKBTHCTTD-UHFFFAOYSA-N
Wiswesser Line Notation	ZN O
LabNetwork Molecule ID	LN03298708
MDL Number	MFCD00011300
CAS Number	1314-13-2
Canonical SMILES	[Zn]=O

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产品应用

常用于于制备新型手性骨架材料 NaZnSiO3OH，可应用于离子交换、吸附或催化。

安全信息

GHS Symbol

WGK Germany2

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P273 Avoid release to the environment. 避免释放到环境中。
P305+P351+P338
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H302 Harmful if swallowed 吞食有害
H319 Causes serious eye irritation 严重刺激眼睛
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
H226 Flammable liquid and vapour 易燃液体和蒸气

Signal word Danger Warning

Personal Protective Equipment Eyeshields, Gloves dust mask type N95 (US), Gloves

RTECSZH4810000

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；

Packing GroupIII

UN Number 3077 UN3082

Risk Statements

R10 Flammable 易燃
R11 Highly flammable 非常易燃
R20 Harmful by inhalation 吸入有害
R50/53
R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥

Hazard Codes 9

Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 240 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ZDKAA8 Zdravookhranenie Kazakhstana.  Public Health of Kazakhstan.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1941-
   Volume(issue)/page/year: 38(9),18,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 7950 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(4),89,1986

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2500 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IPSTB3 International Polymer Science and Technology.  (Rapra Technology
   Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
   3,93,1976

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YAKUD5 Gekkan Yakuji.  Pharmaceuticals Monthly.  (Yakugyo Jihosha, Inaoka
   Bldg., 2-36 Jinbo-cho, Kanda, Chiyoda-ku, Tokyo 101, Japan)  V.1-   1959-
   Volume(issue)/page/year: 22,291,1980

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPO

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 1 mg/L
REFERENCE :
   SHIGAZ Shigaku.  Ondotology.  (Nippon Shika Daigaku Shigakkai, 1-9-20
   Fujimi, Chiyodaku, Tokyo 102, Japan)  V.38-    1949-
   Volume(issue)/page/year: 74,1385,1987

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 1 mg/L
REFERENCE :
   SHIGAZ Shigaku.  Ondotology.  (Nippon Shika Daigaku Shigakkai, 1-9-20
   Fujimi, Chiyodaku, Tokyo 102, Japan)  V.38-    1949-
   Volume(issue)/page/year: 74,1385,1987

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 300 ug/L
REFERENCE :
   SHIGAZ Shigaku.  Ondotology.  (Nippon Shika Daigaku Shigakkai, 1-9-20
   Fujimi,

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 100 ug/m3
REFERENCE :
   CYGEDX Cytology and Genetics (English Translation).  Translation of TGANAK.
   (Allerton Press Inc., 150 Fifth Ave., New York, NY 10011)  V.8-    1974-
   Volume(issue)/page/year: 12(3),46,1978

TYPE OF TEST            : DNA adduct
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 3000 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,95,1981

TYPE OF TEST            : Unscheduled DNA synthesis
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - guinea pig
DOSE/DURATION           : 5300 ug/m3/3H/6D
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   78,29,1985

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 6846 mg/kg
SEX/DURATION            : female 1-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - homeostasis
   Reproductive - Effects on Newborn - stillbirth
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   JONUAI Journal of Nutrition.  (Subscription Dept., 9650 Rockville Pike,
   Bethesda, MD 20014) V.1-    1928-  Volume(issue)/page/year: 98,303,1969

其他信息

其他用途:主要用作橡胶或电缆的补强剂，以使橡胶具有良好的耐腐蚀性，抗撕裂性和弹性。也用作天然橡胶的硫化活化剂，白色橡胶的着色剂和填料，氯丁橡胶的硫化剂。颗粒细小者(粒径0.1μm左右)可用作聚烯烃或聚氯乙烯等塑料的光稳定剂。
海关编码:28170000
防护措施:中毒者会出现食欲不佳、烦渴、疲倦、胸闷及压痛、嗜睡、干咳、并出现体温升高、瞳孔扩大、结膜及咽部、面部充血、糖尿，有时还出现肝大。重者出现肺间质水肿，肺泡上皮破坏。发生中毒可吸入碱性物质、静脉注射葡萄糖（40%溶液20ml)和300mg抗坏血酸。根据症状服用强心剂。空气中最高容许浓度0.5mg/m3。操作中应戴防毒口罩，防护眼镜，穿工作服。工作后热水沐浴。要注意防止蒸气及气溶胶形成及排放到工作地点空气中。应注意防尘通风。
用途十:用于静电湿法复印、干法转印、激光传真通讯、电子计算机的静电记录及静电制版档
所属类别三:饲料添加剂: 矿物质添加剂
使用限量:以GMP为限(FDA，§182．5991，2000)。 GB 2760—2001：即食早餐谷物食品，37.5～
下游产品:碳酸锌 --> 2-溴-6-甲基-4-硝基苯胺 --> GD可见光固化复合树脂 --> 金属镉 --> 杆菌肽 --> 葡萄糖酸锌 --> 硼酸锌 --> 2-氨基苯酚-4-磺酸 --> 硬脂酸锌 --> 磷酸锌 --> 碳酸锌氢氧化物 --> 脱硫剂 --> 镉黄 --> 一水合氢氧化钡 --> 六水合硝酸锌 --> 氟硅酸锌 --> 柴油重油添加剂A型 --> LDR-501-YZ氯丁胶乳 --> 3-乙酰胺基苯乙酮 --> 铬酸锌(1:1) --> 氟硼酸锌 --> 沥青船底防污漆 --> 醋酸锌 --> 磷化液 --> 一水硫酸锌 --> 丁酸丁酯 --> 磷酸二氢锌 --> 钼酸锌 --> 溴化锌 --> 磷化剂 --> 一氧化碳低温变换催化剂 --> 硼酸锌 --> 硝酸锌 --> 乳酸锌 --> 硼酸锌 --> 锌黄 --> 磷酸二氢锌 --> 甘氨酸锌 --> 醋酸锌 --> 柠檬酸锌
氢氧化锌和氧化锌:在Zn2+的可溶盐的溶液中加入适量的碱，可以沉淀出白色的氢氧化锌：Zn 2+ + 2NaOH=Zn(OH)2+2Na + 成四羟基合锌酸Zn(OH)2是两性的氢氧化物，既可溶于酸生成锌盐，又可溶于强碱生成配离子，或称为锌酸盐：Zn(OH) 2 +2H + =Zn 2+ +2H 2 O Zn(OH) 2 +2OH - =[Zn(OH) 4 ] 2- Zn(OH)2还能溶于NH3水中生成四氨合锌酸根配离子，而Al(OH)3则不溶于NH3水：Zn(OH) 2 +4NH3=[Zn(NH3)4] 2+ +2OH - 这也是区别Al(OH)3和Zn(OH)2的方法之一。 Zn(OH)2受热时易脱水生成白色的氧化锌ZnO：Zn(OH) 2 ==加热==ZnO+H2O [Zn(OH)4]2-和[Zn(NH3)4]2+ 在加热或加酸的条件下，配离子解体，又生成Zn(OH)2：[Zn(NH3)4] 2+ +2OH-==加热==Zn(OH)2+4NH3Zn(OH)2和ZnO都是共价型的化合物。Zn(OH)2常常用作造纸的填料。 ZnO是一种著名的白色的颜料，俗名叫锌白。它的优点是遇到H2S气体不变黑，因为ZnS也是白色的。在加热时，ZnO由白、浅黄逐步变为柠檬黄色，当冷却后黄色便退去，利用这一特性，把它掺入油漆或加入温度计中，做成变色油漆或变色温度计。因ZnO有收敛性和一定的杀菌能力，在医药上常调制成软膏使用，ZnO还可用作催化剂。在Zn2+盐中加入Na2CO3溶液，得到的是碱式碳酸锌的白色沉淀，而不是Zn(OH)2：2Zn 2+ +2CO 3 2- +2H2O===Zn2(OH)2CO3+2HCO3-
参考质量标准四:FCC-1981 含量/% ≥99.0 碱度试验正常砷(以As计)/% ≤0.0003 镉/% ≤0.001 铅/% ≤0.001 灼烧失重/% ≤1.0 非硫化物沉淀物质/% ≤0.5
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纳米氧化锌在防晒化妆品中的应用:由于地球臭氧层遭到破坏，导致紫外线对地球生物圈辐射量的不断增加，过多的紫外线照射对人类健康造成的危害正在
参考质量标准一:指标名称指标(工业级) 一等品合格品外观白色或微黄色微细粉末氧化锌(Z